Alleima® 254 SMO Tube and pipe, seamless

Datasheet updated

2022-06-29 14:44
(supersedes all previous editions)

Alleima® 254 SMO is a high-alloy austenitic stainless steel developed for use in seawater and other aggressive chloride-bearing media. The steel is characterized by the following properties:

  • Excellent resistance to pitting and crevice corrosion, PRE = ≥42.5*
  • High resistance to general corrosion
  • High resistance to stress corrosion cracking
  • Higher strength than conventional austenitic stainless steels
  • Good weldability

*The PRE is defined as, in weight-%, PRE = %Cr + 3.3 x %Mo + 16 x %N

Trademark information: 254 SMO is a trademark owned by Outokumpu OY.

Standards

  • UNS: S31254
  • EN Number: 1.4547
  • EN Name: X1CrNiMoCuN20-18-7
  • W.Nr.: 1.4529**
  • AFNOR: Z1 CNDU 20.18.06AZ*

* Obsolete. Replaced by EN.
** Nearest equivalent grade.

Product standards

  • Seamless tube and pipe: ASTM A269, A213, A312, NFA 49-217, EN 10216-5
  • Norsok MDS R11/R18, IOGP S-563 MDS IR111/111S/IR118/IR118S
  • Welded tube and pipe: ASTM A249, A269 , A312, A358, A409
  • Fittings: ASTM A182
  • Bar: ASTM A276, A479, EN 10088-3
  • Forged products: ASTM A473

Approvals

  • UNS S31254 (Alleima® 254 SMO) in the form of seamless pipe has been approved by the American Society of Mechanical Engineers (ASME) for use according to ASME Boiler and Pressure Vessel Code section VIII, div. 1. However, there is no approval for UNS S31254 in the form of seamless tube, but according to the ASME paragraph UG-15 it is allowed to use the design values for seamless pipe according to ASME section VIII, div. 1 also for seamless tube.
  • NACE MR 0175 (sulphide stress cracking resistant material for oil field equipment).

Chemical composition (nominal)

Chemical composition (nominal) %
C Si Mn P S Cr Ni Mo N Cu
≤0.020 ≤0.80 ≤1.00 ≤0.030 ≤0.010 20 18 6.1 0.20 0.7

Chemical composition (nominal) %

C Si Mn P S Cr Ni Mo N Cu
≤0.020 ≤0.80 ≤1.00 ≤0.030 ≤0.010 20 18 6.1 0.20 0.7

Applications

Alleima 254 SMO is used in the following applications:

  • Equipment for handling of seawater, such as seawater cooling, cooling water pipes, ballast water systems, firefighting systems etc.
  • Hydraulic and instrumentation tubing
  • Equipment in pulp bleaching plants
  • Components in gas cleaning systems
  • Tanks and pipelines for chemicals with high halide contents

Trademark information: 254 SMO is a trademark owned by Outokumpu OY.

Corrosion resistance

In solutions containing halides such as chloride and bromide ions, conventional stainless steels can be readily attacked by local corrosion in the form of pitting corrosion, crevice corrosion or stress corrosion cracking (SCC). In acid environments, the presence of halides also accelerates general corrosion.

General corrosion

In pure sulphuric acid, Alleima 254 SMO is much more resistant than ASTM TP316, and in naturally aerated sulphuric acid containing chloride ions Alleima 254 SMO exhibits higher resistance than '904L', see Figure 2.

Figure 2. Isocorosion diagram 0.1 mm/year (4mpy) in naturally aerated sulphuric acid containing 2000 ppm chloride ions.

Stress corrosion cracking (SCC)

Ordinary austenitic steels of the ASTM TP304 and TP316 type are prone to stress corrosion cracking (SCC) in chloride-containing solutions at temperatures exceeding about 60°C (140°F). For the austenitic steels, resistance to SCC increases with higher nickel and molybdenum contents. The tables below show the results of two accelerated tests, clearly demonstrating that Alleima 254 SMO has a very good resistance to SCC.

Stress corrosion cracking tests in boiling 25% NaCl solution, pH=1.5. U-bend specimens.
Grade Time to failure Remark
ASTM TP316
<150 h
Pitting
'904L'
No failure (1000 h)
Crevice corrosion
Sandvik 254 SMO
No failure (1000 h)
No attack
Stress corrosion cracking tests. Drop evaporation method*. Stress: 0.9xRp0.2
Grade Time to failure hours
ASTM TP316
105
'904L'
225
Sandvik 254 SMO
425

* A 0.1 M NaCl solution is allowed to drop slowly onto an electrically heated
tensile test specimen at 300 oC (570 oF).

Intergranular corrosion

Alleima 254 SMO has a very low carbon content. This means that there is very little risk of carbide precipitation during heating, for example when welding. The steel passes the Strauss test (ASTM A262, practice E) even after sensitizing for one hour at 600–1000°C (1110–1830°F).

However, due to the high alloying content of the steel, inter-metallic phases can precipitate at the grain boundaries in the temperature range 600–1000°C (1110–1830°F). These precipitations do not involve any risk of intergranular corrosion in the environments in which the steel is intended to be used. Thus, welding can be carried out without any risk of intergranular corrosion.

Pitting corrosion

The pitting and crevice corrosion resistance of stainless steel is primarily determined by the content of chromium, molybdenum and nitrogen. Manufacture and fabrication, e.g. welding, are also of vital importance for the actual performance in service. A parameter for comparing the resistance to pitting in chloride environments is the PRE number (Pitting Resistance Equivalent). The PRE is defined as, in weight-%, PRE = %Cr + 3.3 x %Mo + 16 x %N

PRE-value for Alleima 254 SMO = ≥42,5.

The results of laboratory determination of the critical pitting temperature (CPT) in 3 % NaCl are shown in Figure 3, where it can be seen that Alleima 254 SMO possesses very good resistance in water containing chlorides. Alleima 254 SMO is, therefore, a suitable material for use in seawater.

Crevice corrosion

The weak point of conventional stainless steels is their limited resistance to crevice corrosion. In seawater, for example, there is a considerably greater risk of crevice corrosion under gaskets, deposits or fouling. Tests in natural seawater at 60°C (140°F) have shown that Alleima 254 SMO can be exposed for prolonged periods without suffering crevice corrosion. Figure 4 shows the results of accelerated crevice corrosion tests.

Figure 3. Critical pitting temperature (CPT) in 3% NaCl, 600 mV/SCE.

Figure 4. Critical crevice corrosion temperature in FeCl₃ for Sandvik 254 SMO, AISI 316L and 904L. According to ASTM G-48.

Fabrication

Avoid abrasion against copper/copper alloys or other similar metals which, if present in metallic form, can cause cracks during subsequent welding, hot processing or heat treatment.

Bending

The excellent formability of Alleima 254 SMO permits cold bending to very tight bending radii. Annealing is not normally necessary after cold bending.

Machining

Alleima 254 SMO is a high alloyed austenitic stainless steel and thus tougher inserts in metal cutting are needed than is the case for lower alloyed austenitic grades. When machining Alleima 254 SMO considerably lower cutting speeds are recommended compared to the grades Sanmac 304/304L and Sanmac 316/316L, which have improved machinability.

Forms of supply

Seamless tube and pipe are supplied in dimensions up to 230 mm (9.06 in.) outside diameter. The delivery condition is either solution annealed and white pickled, or solution annealed in a bright annealing process.

Other forms of supply

  • Welded tube and pipe
  • Fittings and flanges
  • Bar steel
  • Forged products
  • Cast products

Heat treatment

The tubes are delivered in heat treated condition. If additional heat treatment is needed due to further processing the following is recommended.

Solution annealing

1150–1200°C (2100–2190°F), quenching in water. Thin-walled tubes min. 1130°C (2060°F), quenching in air/water.

Mechanical properties

The following figures apply to solution annealed condition seamless tube and pipe.

Metric units, at 20°C
Wall thickness Proof strength Tensile strength Elong. Hardness
Rp0.2a) Rp1.0a) Rm Ab) A2" HRB
mm MPa MPa MPa % %
<5 ≥310 ≥340 675-850 ≥35 ≥35 ≤96
>5 ≥310 ≥340 655-850 ≥35 ≥35 ≤96

1 MPa = 1 N/mm2

Imperial units, at 68°F
Wall thickness Proof strength Tensile strength Elong. Hardness
Rp0.2a) Rp1.0a) Rm Ab) A2" HRB
inch ksi ksi ksi % %
<0.187 ≥45 ≥49 98-123 ≥35 ≥35 ≤96
>0.187 ≥45 ≥49 98-123 ≥35 ≥35 ≤96

a) Rp0.2 and Rp1.0 correspond to 0.2% offset and 1.0% offset yield strength, respectively.
b) Based on L0 = 5.65 √S0 where L0 is the original gauge length and S0 the original cross-section area.

Impact strength

Due to its austenitic microstructure, Alleima 254 SMO has very good impact strength both at room temperature and at cryogenic temperatures.

Tests have demonstrated that the steel fulfils the requirements (60 J (44 ft-lb) at -196 oC (-320 oF)) according to the European standards EN 13445-2 (UFPV-2) and EN 10216-5.

At high temperatures

Intermetallic phases are precipitated within the temperature range of 600–1000°C (1110–1830°F). Therefore, the steel should not be exposed to these temperatures for prolonged periods.

Metric units
Temperature
Proof strength
°C Rp0.2 Rp1.0
MPa MPa
min. min.
100 230 270
200 190 225
300 170 200
400
160
190
500 148 180
Imperial units
Temperature
Proof strength
°F Rp0.2 Rp1.0
ksi ksi
min. min.
200 34 40
400 27 32
600 24 29
700
24
28
900 22 26

Figure 1. Strength values (min. values) for Sandvik 254SMO and allowable stress according to ASME Boiler and Pressure Vessel Code section VIII, div. 1.

Physical properties

Density: 8.0 g/cm3, 0.29 lb/in3

Thermal conductivity
Temperature, oC W/m oC Temperature, oF Btu/ft h oF
20 10 68 6
100 12 200 7
200 14 400 8
300 16 600 9.5
400 18 800 10.5
500 20 1000 11.5
600 21 1200 12.5
700 23 1300 13
Specific heat capacity
Temperature, °C
J/kg °C
Temperature, °F Btu/ft h °F
20 485 68 0.12
100 510 200 0.12
200 535 400 0.13
300 565 600 0.14
400 585 800 0.14
500 600 1000 0.14
600 615 1200 0.15
700
625
1400 0.15
Thermal expansion, mean values in temperature ranges (x106)
Temperature, °C
Per °C
Temperature, °F Per °F
30–100 16 86–200 9
30–200 16 86–400 9
30–300 16.5 86–600 9
30–400 16.5 86–800 9.5
30–500 17 86–1000 9.5
30–600 17 86–1200 9.5
30–700
17.5
86–1300 10
Modulus of elasticity, (x103)
Temperature, °C
MPa
Temperature, °F ksi
20 195 68 28.3
100 190 200 27.6
200 182 400 27.5
300 174 600 25.1
400 166 800 23.8
500
158
1000 22.5

Welding

The weldability of Alleima 254 SMO is good. Suitable methods of fusion welding are manual metal-arc welding (MMA/SMAW) and gas-shielded arc welding, with the TIG/GTAW method as first choice.

In common with all fully austenitic stainless steels, Alleima 254 SMO has low thermal conductivity and high thermal expansion. Welding plans should therefore be carefully selected in advance, so that distortions of the welded joint are minimized. If residual stresses are a concern, solution annealing can be performed after welding.

For Alleima 254 SMO, heat-input of <1.5 kJ/mm and interpass temperature of <100°C (210°F) are recommended. A string bead welding technique should be used.

Nickel alloys with high molybdenum and chromium must be used as filler metals to have good corrosion resistance in the as-welded condition.

Recommended filler metals

TIG/GTAW or MIG/GMAW welding

ISO 18274 S Ni 6625/AWS A5.14 ERNiCrMo-3 (e.g. Exaton Ni60)

ISO 18274 S Ni 6059/AWS A5.14 ERNiCrMo-13 (e.g. Exaton Ni59)

MMA/SMAW welding

ISO 14172 E Ni 6625/AWS A5.11 ENiCrMo-3 (e.g. Exaton Ni60)

ISO 14172 E Ni 6059/AWS A5.11 ENiCrMo-13 (e.g. Exaton Ni59)

Disclaimer: Recommendations are for guidance only, and the suitability of a material for a specific application can be confirmed only when we know the actual service conditions. Continuous development may necessitate changes in technical data without notice. This datasheet is only valid for Alleima materials.