Alleima® 2C48 Tube and pipe, seamless

Datasheet updated

2022-06-29 14:45
(supersedes all previous editions)

Alleima® 2C48 is a ferritic, heat resisting, stainless chromium steel, characterized by:

  • Good resistance to reducing sulphurous gases
  • Very good resistance to oxidation in air
  • good resistance to oil-ash corrosion
  • Resistance to molten copper, lead and tin

This steel can be used at temperatures up to 1075°C (1970°F). However, allowance should be made for the low creep strength at the highest temperatures in order to avoid distortion due to the mass of the steel.

Standards

  • ASTM: 446-2
  • UNS: S44600

Product standards

  • ASTM A268

Chemical composition (nominal)

Chemical composition (nominal) %
C Si Mn P S Cr N
0.09 0.5 0.8 ≤0.030 ≤0.015 23.5 0.2

Chemical composition (nominal) %

C Si Mn P
S
Cr N
0.09 0.5 0.8 ≤0.030 ≤0.015 23.5 0.2

Applications

Typical applications for Alleima® 2C48 are:

  • Recuperators in the metallurgical and glass industries
  • Thermocouple protection tubes
  • Cable tubing
  • Sootblower tubes
  • Injection nozzles

Corrosion resistance

Air

Alleima® 2C48 is highly resistant to oxidation, both at constant and at cyclically varying temperatures. The service temperature in air should not exceed about 1075°C (1970°F).

Hot corrosion / sulphidation

Owing to its high chromium content and the absence of nickel, Alleima® 2C48 has very good resistance in sulphidizing gases and salts. The steel has relatively good resistance to slags containing vanadium pentoxide and sodium sulphate, for example, which are extremely aggressive at temperatures above 600°C (1110°F).

Nitrogen pick-up

Nitrogen pick-up can occur in gas mixtures with low oxygen concentrations and high concentrations of nitrogen, cracked ammonia or mixtures of nitrogen and hydrogen. Nitrogen pick-up leads to embrittlement and reduced oxidation resistance. Alleima® 2C48 is more sensitive than austenitic steels in environments where nitrogen pick-up can occur.

Carburizing atmosphere
When a material comes into contact with hot gases containing hydrocarbons and carbon monoxide, carburization can occur. The extent of carburization depends on the composition of the material and of the gas.

The relatively high chromium content of Alleima® 2C48 promotes the formation of a protective oxide layer on the surface of the material, providing some protection against carburization.

However, because Alleima® 2C48 is ferritic, carburization occurs quickly, if the oxide layer cracks or if the oxygen content is too low to form a protective oxide layer. For this reason, the material does not possess the same resistance as the austenitic steels, for example, Alleima® 253 MA* or Sanicro 31HT.

Metal and salt baths

The ferritic structure of Alleima® 2C48 gives it good resistance in baths of molten copper. It also possesses good resistance in other molten metals, such as lead, tin, bearing metals, brass and magnesium. In these metals, it is a good idea to use replaceable sleeves of ceramic material or graphite, since corrosion is heaviest at the surface of the metal bath. In salt baths for heat treatment etc., such as cyanide baths and neutral salt baths, austenitic alloys with a high nickel content should be chosen instead (e.g. Sanicro 31HT).

* 253 MA is a trademark owned by Outokumpu OY.

Bending

Generally Alleima® 2C48 has improved bending properties, compared with ASTM TP446-1.

When Alleima® 2C48 tubes are to be bent cold, we recommend the use of cold-worked tubes. Annealing is not normally necessary after cold bending.

Hot-worked tubes should preferably be bent hot, but they can be bent cold, if the bending radius is greater than 5 times the diameter.

Hot bending is carried out at 1000–800°C (1830–1470°F) and should be followed by annealing, if necessary for reasons of design.

Forms of supply

Seamless tube and pipe in Alleima® 2C48 is supplied in dimensions up to 120 mm outside diameter in the annealed condition, but is also available white-pickled after annealing.

Heat treatment

Tubes are delivered in the heat treated condition. If another heat treatment is needed after further processing, the following is recommended:

Stress relieving

800–850°C (1470–1560°F), 15–30 minutes, rapid cooling in air.

Annealing

800–900°C (1470–1650°F), 30–60 minutes, rapid cooling in air.

Mechanical properties

Metric units, at 20°C
Proof strength Tensile strength Elong. Hardness
Rp0.21) Rm A2"
MPa MPa % HRB
≥275 ≥450 ≥20 ≤95

1 MPa = 1 N/mm2

Imperial units, at 68°F
Proof strength Tensile strength Elong. Hardness
Rp0.21) Rm A2"
ksi ksi % HRB
≥40 ≥65 ≥20 ≤95

1) Rp0.2 and Rp1.0 correspond to 0.2% offset and 1.0% offset yield strength, respectively.
2) Based on L0 = 5.65 √S0, where L0 is the original gauge length and S0 the original cross-sectional area.

The creep strength for Alleima® 2C48 is slightly inferior to that of Alleima® 4C54 (ASTM TP446-1).

Physical properties

Density: 7.6 g/cm3, 0.27 lb/in3


Thermal conductivity
Temperature, °C W/(m °C) Temperature, °F Btu/(ft h °F)
20 20 68 11.5
100 21 200 12.5
200 22 400 12.5
300 23 600 13
400 23 800 13.5
500 24 1000 14.5
600 25 1200 14
700 24 1400 14.5
800 26 1600 15.5
900 28 1800 17
1000 30 2000 19
1100 34

Specific heat capacity
Temperature, °C J/(kg °C) Temperature, °F Btu/(lb °F)
20 475 68 0.11
100 520 200 0.12
200 555 400 0.13
300 595 600 0.14
400 625 800 0.16
500 710 1000 0.18
600 795 1200 0.18
700 720 1400 0.17
800 695 1600 0.16
900 680 1800 0.17
1000 715 2000 0.18
1100 760

Thermal expansion1)
Temperature, °C Per °C Temperature, °F Per °F
30-100 10 86-200 5.5
30-200 10 86-400 5.5
30-300 10.5 86-600 6
30-400 11 86-800 6
30-500 11 86-1000 6
30-600 11.5 86-1200 6.5
30-700 11.5 86-1400 6.5
30-800 12 86-1600 7
30-900 13 86-1800 7.5
30-1000 13.5

1) Mean values in temperature ranges x10-6

Modulus of elasticity1)
Temperature, °C MPa Temperature, °F ksi
20 195 68 28.5
200 190 400 27.5
400 180 800 25.5
600 145 1200 20.5
800 125 1400 18.5
1000 120 1800 17.5

1) x 103

Structural stability

Temperatures of about 400–550°C (750–1020°F) should be avoided for even short periods of time, whether the steel is in service or merely being held at that temperature, since severe embrittlement, known as 475 deg. embrittlement, can take place. This is noticeable after the tubes have cooled to room temperature. However, the steel can be restored to its original condition by short term heating at a temperature above 600°C (1110°F).

Embrittlement can also occur as a result of sigma phase formation after prolonged service at 550–750°C (1020–1380°F). The sigma phase can be redissolved after a heat treatment above 900°C (1650°F).

Welding

The weldability of Alleima® 2C48 is good. Welding must be carried out with preheating at 200-300°C (390-570°F), subsequent heat treatment is not required where Alleima® 2C48 is used in structures that operate for prolonged periods at high temperature. Suitable methods of fusion welding are manual metal-arc welding (MMA/SMAW) and gas-shielded arc welding, with the TIG/GTAW method as first choice.

For Alleima® 2C48, heat-input of <1.5 kJ/mm and interpass temperature of <150°C (300°F) are recommended.

Recommended filler metals

TIG/GTAW welding

ISO 14343 S 29 9/AWS A5.9 ER312 (e.g. Exaton 29.9) or

ISO 14343 S 25 20/AWS A5.9 ER310 (e.g. Exaton 25.20.C) or

ISO 18274 S Ni 6082/AWS A5.14 ERNiCr-3 (e.g. Exaton Ni72HP)

MMA/SMAW welding

ISO 3581 E 29 9 R/AWS A5.4 E312-16 (e.g. Exaton 29.9.R) or

ISO 3581 E 25 20 B/AWS A5.4 E310-16 (e.g. Exaton 25.20.B) or

ISO 14172 E Ni 6182/AWS A5.11 ENiCrFe-3 (e.g. Exaton Ni71)

When using the austenitic stainless-steel wire electrode S 25 20/ER310 and the covered electrode E 25 20 B/E310-16, the higher thermal expansion of the austenitic weld metal must be considered.

When using nickel alloy wire electrode S Ni 6082/ERNiCr-3 and covered electrode E Ni 6182/ENiCrFe-3, however, allowance must be made for lower corrosion resistance of the steel welded joint in a reducing sulphurous atmosphere.

Disclaimer: Recommendations are for guidance only, and the suitability of a material for a specific application can be confirmed only when we know the actual service conditions. Continuous development may necessitate changes in technical data without notice. This datasheet is only valid for Alleima materials.